Triethylamine → 1,1,1,3,3-Pentachloro-1,3-disilabutane

HRID 1068511Notes

Reaction equation

HRID 1068511 reaction equation
C(N(CC)CC)C.Cl[CH2:9][Si:10]([CH3:13])([Cl:12])[Cl:11].[Cl:14][SiH:15]([Cl:17])[Cl:16]>>[Cl:14][Si:15]([Cl:17])([Cl:16])[CH2:9][Si:10]([Cl:12])([Cl:11])[CH3:13]

Participants

4

Reactant 3

HCID 8471TriethylamineHCID 24811TrichlorosilaneHCID 73788Dichloro(chloromethyl)methylsilane

Product 1

HCID 126086481,1,1,3,3-Pentachloro-1,3-disilabutaneYield 31%

Procedure

In the same apparatus and procedure as Example 1 above, 0.063 g (0.62 mmol) of triethylamine, 1.0g (6.2 mmol) of (chloromethyl)methyldichlorosilane, and 4.18 g (30.9 mmol) of trichlorosilane were reacted at 200° C. for 24 hrs. The resulting mixture was distilled to give 0.50 g of 1,1,1,3,3-pentachloro-1,3-disilabutane (yield; 31%).

Workup

  1. distillationThe resulting mixture was distilled

Sources & evidence

ORD record
ord-262d3fd3cd5f4b8691ffccdb2c9a1afc
Source dataset
uspto-grants-2001_06
Patent number
US06251057B1

Reaction notes

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