Tributylamine → 1,1,1,3,3-Pentachloro-1,3-disilabutane

HRID 1068512Notes

Reaction equation

C(N(CCCC)CCCC)CCC.Cl[CH2:15][Si:16]([CH3:19])([Cl:18])[Cl:17].[Cl:20][SiH:21]([Cl:23])[Cl:22]>>[Cl:20][Si:21]([Cl:23])([Cl:22])[CH2:15][Si:16]([Cl:18])([Cl:17])[CH3:19]

Participants

Reactant 3

HCID 7622Tributylamine

HCID 24811Trichlorosilane

HCID 73788Dichloro(chloromethyl)methylsilane

Product 1

HCID 126086481,1,1,3,3-Pentachloro-1,3-disilabutaneYield 30.7%

Procedure

In the same apparatus and procedure as Example 1 above, 0.115 g (0.62 mmol) of tri-n-butylamine, 1.0 g (6.2 mmol) of (chloromethyl)methyldichlorosilane, and 4.18 g (30.9 mmol) of trichlorosilane were reacted at 200° C. for 11 hrs. The resulting mixture was distilled to give 0.50 g of 1,1,1,3,3-pentachloro-1,3-disilabutane (yield; 6%).

Workup

distillationThe resulting mixture was distilled

Sources & evidence

ORD record: ord-33eaf5d09b8f4dc28c856636086109d6
Source dataset: uspto-grants-2001_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06251057B1

Reaction notes

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