Trichlorosilane → p-Methoxybenzyltrichlorosilane

HRID 1068527Notes

Reaction equation

HRID 1068527 reaction equation
C1(P(C2CCCCC2)C2CCCCC2)CCCCC1.[CH3:20][O:21][C:22]1[CH:29]=[CH:28][C:25]([CH2:26]Cl)=[CH:24][CH:23]=1.[Cl:30][SiH:31]([Cl:33])[Cl:32]>>[CH3:20][O:21][C:22]1[CH:29]=[CH:28][C:25]([CH2:26][Si:31]([Cl:33])([Cl:32])[Cl:30])=[CH:24][CH:23]=1

Participants

4

Reactant 3

HCID 24811TrichlorosilaneHCID 699934-Methyloxybenzyl chlorideHCID 75806Tricyclohexylphosphine

Product 1

HCID 11482253p-MethoxybenzyltrichlorosilaneYield 47%

Procedure

In the same apparatus and procedure as Example 1 above, 0.056 g (0.2 mmol) of tricyclohexylphosphine, 0.271 ml (2.0 mmol) of 4-methoxybenzyl chloride, and 1.00 ml (9.91 mmol) of trichlorosilane were reacted at 150° C. for 2 hrs. The resulting mixture was distilled to give 0.23 g of (4-methoxybenzyl)trichlorosilane (yield; 47%).

Workup

  1. distillationThe resulting mixture was distilled

Sources & evidence

ORD record
ord-7f0e29b6cb2643ba89a860d4449c7cd7
Source dataset
uspto-grants-2001_06
Patent number
US06251057B1

Reaction notes

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