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HRID1069069

反应详情

EQUATION

反应方程式

HRID 1069069 的结构方程式

REACTANTS

反应物

2
结构：O=[N+]([O-])c1cccc(B(O)O)c1
HCID1677

Boronic acid, (3-nitrophenyl)-

C6H6BNO4

结构：COC(=O)c1cccc(Br)c1
HCID12070

Benzoic acid, 3-bromo-, methyl ester

C8H7BrO2

PRODUCTS

生成物

1
结构：COC(=O)c1cccc(-c2cccc([N+](=O)[O-])c2)c1
HCID11708671

Methyl 3-(3-nitrophenyl)benzoate

C14H11NO4

AUXILIARIES

试剂、催化剂与溶剂

1
结构：c1ccc([P](c2ccccc2)(c2ccccc2)[Pd]([P](c2ccccc2)(c2ccccc2)c2ccccc2)([P](c2ccccc2)(c2ccccc2)c2ccccc2)[P](c2ccccc2)(c2ccccc2)c2ccccc2)cc1
催化剂HCID178418397

未命名化合物

PROCEDURE

实验过程

n.m.r. δ values include 3.96 (s, 3 H), 7.57 (t, 1 H), 7.64 (t, 1 H), 7.81 (d, 1 H), 7.94 (d,1 H), 8.09 (d, 1 H), 8.23 (dd, 1 H), 8.30 (s, 1 H), 8.48 (t, 1 H), m.p., 88-90° C.; from methyl 3-bromobenzoate (2.0 g), tetrakis(triphenylphosphine)palladium(0) (348mg) and 3-nitrophenylboronic acid (1.9 g).

WORKUP

后处理

  1. customm.p., 88-90° C.