Potassium Carbonate → HCID 88231394, compound

HRID 1069538Notes

Reaction equation

HRID 1069538 reaction equation
[CH2:1]([C:4]1[CH:5]=[C:6](O)[C:7](=[CH:9][CH:10]=1)[OH:8])[CH2:2][CH3:3].[C:12]([O-])([O-])=[O:13].[K+].[K+]>CN(C=O)C.ClCCl>[CH2:1]([C:4]1[CH:10]=[CH:9][C:7]2[O:8][O:13][CH2:12][C:6]=2[CH:5]=1)[CH2:2][CH3:3]

Participants

4

Reactant 2

HCID 11430Potassium CarbonateHCID 976384-Propyl-1,2-benzenediol

Product 1

HCID 88231394HCID 88231394, compound

Reagents, catalysts & solvents 1

HCID 22350042dichloromethane N,N-dimethylformamideSolvent2×

Conditions

Temperature
117.5 °C

Procedure

4-Propyl catechol (10.7 g; 70 mmols) was dissolved in a 90:10 (v/v) DMF/dichloromethane mixture (17 ml). The resulting solution was added very slowly to a suspension of anhydrous K2CO3 (14.1 g; 87 mmols) in a 90:10 (v/v) DMF/dichloromethane mixture (85 ml), maintained at 115-120° C.

Sources & evidence

ORD record
ord-754526a8f00d4eec8407c1b248acb2b5
Source dataset
uspto-grants-2001_06
Patent number
US06252092B1

Reaction notes

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