1-Hexene → 2-Octanone

HRID 1069804Notes

Reaction equation

HRID 1069804 reaction equation
[CH2:1]([CH2:8][C:9](=[O:11])[CH3:10])[C:2]1C=C[CH:5]=[CH:4][CH:3]=1.C=CCCCC>C1(C)C=CC=CC=1>[CH3:10][C:9](=[O:11])[CH2:8][CH2:1][CH2:2][CH2:3][CH2:4][CH3:5]

Participants

4

Reactant 2

HCID 115971-HexeneHCID 17355Benzyl acetone

Product 1

HCID 80932-Octanone

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Under the same reaction procedure and conditions as in Example 2 (tristriphenylphosphine rhodium (I) chloride 10 mol %, 150° C., 48 hours), benzyl acetone 32 mg (0.22 mmol) and 1-hexene 182 mg (2.16 mmol) were reacted in toluene 100 mg in the presence of various amines (20 mol % based on benzyl acetone). A measurement was made of the yields of 2-octanone and the results are given in Table 5, below.

Sources & evidence

ORD record
ord-f282965ae0584843abc2c38c6072e411
Source dataset
uspto-grants-2001_06
Patent number
US06252118B1

Reaction notes

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