Ammonia → Ferric acetylacetonate

HRID 1071903Notes

Reaction equation

HRID 1071903 reaction equation
[Fe:1](Cl)(Cl)Cl.N.[OH-].[Fe+3].[OH-].[OH-].[C:10]([CH2:13][C:14](=[O:16])[CH3:15])(=[O:12])[CH3:11]>O>[CH3:15]/[C:14](/[O-:16])=[CH:13]/[C:10]([CH3:11])=[O:12].[CH3:15]/[C:14](/[O-:16])=[CH:13]/[C:10]([CH3:11])=[O:12].[CH3:15]/[C:14](/[O-:16])=[CH:13]/[C:10]([CH3:11])=[O:12].[Fe+3:1]

Participants

6

Reactant 4

HCID 222AmmoniaHCID 24380Iron chloride (FeCl3)HCID 31261AcetylacetoneHCID 73964Ferric hydroxide

Product 1

HCID 5483663Ferric acetylacetonate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

20.3 g of anhydrous iron (III) chloride (0.124 mol) was dissolved in 30 g of demineralised water with gentle warming. To this was added 45 ml of ammonia solution (SG. 0.880). The mixture was then heated on a steam bath for 30 minutes. The precipitate of iron (III) hydroxide was filtered and washed free of chloride. The moist iron (III) hydroxide and 60 g of acetylacetone (0.6 mol) were mixed together and heated for 30 minutes. Crystals of Fe(acac)3 were deposited and were recrystallised from ethanol.

Workup

  1. temperatureThe mixture was then heated on a steam bath for 30 minutes
  2. filtrationThe precipitate of iron (III) hydroxide was filtered
  3. washwashed free of chloride
  4. temperatureheated for 30 minutes
  5. customwere recrystallised from ethanol

Sources & evidence

ORD record
ord-ccd0908d2f414fc1bcfe0cb46a487a11
Source dataset
uspto-grants-2005_06
Patent number
US06908875B2

Reaction notes

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