N-vinyl-2-pyrrolidone → Octaneperoxoic acid, 1,1-dimethylethyl ester

HRID 1073042Notes

Reaction equation

HRID 1073042 reaction equation
[CH:1](N1CCCC1=O)=C.[CH:9]1[C:14]([C:15]([O:17][O:18][C:19]([CH3:22])([CH3:21])[CH3:20])=[O:16])=[CH:13][CH:12]=[CH:11][CH:10]=1>>[CH3:1][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:14][C:15]([O:17][O:18][C:19]([CH3:20])([CH3:21])[CH3:22])=[O:16]

Participants

3

Reactant 2

HCID 6917N-vinyl-2-pyrrolidoneHCID 11966tert-Butyl peroxybenzoate2×

Product 1

HCID 83499Octaneperoxoic acid, 1,1-dimethylethyl ester

Conditions

Temperature
130 °C

Procedure

10.76 g of N-vinyl-2-pyrrolidone and the temperature is raised to 130° C. Then 0.9 g of tert-butyl perbenzoate is added. After 1 and 2 hours, respectively, a 0.4 g portion of tert-butyl perbenzoate is fed in. The charge is maintained at 130° C. for another 5 hours. A clouded viscous solution is obtained.

Workup

  1. customAfter 1 and 2 hours
  2. customA clouded viscous solution is obtained

Sources & evidence

ORD record
ord-b77ca60e80ca4d93b19c71c6d8eaba75
Source dataset
uspto-grants-1990_11
Patent number
US04968444

Reaction notes

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