Hydroxylamine → HCID 86744351, compound

HRID 1073976Notes

Reaction equation

[CH3:1][C:2]1([CH3:62])[CH2:7][CH:6]([N:8]([CH:50]2[CH2:55][C:54]([CH3:57])([CH3:56])[NH:53][C:52]([CH3:59])([CH3:58])[CH2:51]2)[C:9]([C:11]2[CH:49]=[CH:48][C:14]([CH2:15][N:16]([CH2:18][C:19]3[CH:24]=[CH:23][C:22]([C:25]([N:27]([CH:38]4[CH2:43][C:42]([CH3:45])([CH3:44])[NH:41][C:40]([CH3:47])([CH3:46])[CH2:39]4)[CH:28]4[CH2:33][C:32]([CH3:35])([CH3:34])[NH:31][C:30]([CH3:37])([CH3:36])[CH2:29]4)=[O:26])=[CH:21][CH:20]=3)[OH:17])=[CH:13][CH:12]=2)=[O:10])[CH2:5][C:4]([CH3:61])([CH3:60])[NH:3]1.CC1(C)CC(N(C2CC(C)(C)NC(C)(C)C2)C(=O)C2C=CC(CCl)=CC=2)CC(C)(C)N1.NO>>[CH3:44][C:42]1([CH3:45])[CH2:43][CH:38]([N:27]([CH:28]2[CH2:29][C:30]([CH3:37])([CH3:36])[NH:31][C:32]([CH3:35])([CH3:34])[CH2:33]2)[C:25]([C:22]2[CH:21]=[CH:20][C:19]([CH:18]=[N+:16]([CH2:15][C:14]3[CH:13]=[CH:12][C:11]([C:9]([N:8]([CH:50]4[CH2:51][C:52]([CH3:58])([CH3:59])[NH:53][C:54]([CH3:57])([CH3:56])[CH2:55]4)[CH:6]4[CH2:7][C:2]([CH3:1])([CH3:62])[NH:3][C:4]([CH3:60])([CH3:61])[CH2:5]4)=[O:10])=[CH:49][CH:48]=3)[O-:17])=[CH:24][CH:23]=2)=[O:26])[CH2:39][C:40]([CH3:47])([CH3:46])[NH:41]1

Participants

Reactant 3

HCID 787Hydroxylamine

HCID 22902712HCID 22902712, compound

HCID 22902721HCID 22902721, compound

Product 1

HCID 86744351HCID 86744351, compound

Procedure

Following the general procedure of Example 6, the title compound is prepared from N,N-bis[4-(N,N-bis(2,2,6,6-tetramethylpiperidin-4-yl)aminocarbonyl)benzyl]hydroxylamine. Said intermediate is prepared from N,N-bis(2,2,6,6-tetramethylpiperidin-4-yl)-4-chloromethylbenzamide and hydroxylamine.

Sources & evidence

ORD record: ord-6bad277a3929491b8145e735243ae6b9
Source dataset: uspto-grants-1990_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04972009

Reaction notes

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