2,5-Dichloronitrobenzene → HCID 15077494, compound

HRID 1074194Notes

Reaction equation

HRID 1074194 reaction equation
Cl[C:2]1[CH:7]=[CH:6][C:5]([Cl:8])=[CH:4][C:3]=1[N+:9]([O-:11])=[O:10].[SH:12][C:13]1[N:14]([CH3:18])[CH:15]=[CH:16][N:17]=1>>[Cl:8][C:5]1[CH:6]=[CH:7][C:2]([S:12][C:13]2[N:14]([CH3:18])[CH:15]=[CH:16][N:17]=2)=[C:3]([N+:9]([O-:11])=[O:10])[CH:4]=1

Participants

3

Reactant 2

HCID 69772,5-DichloronitrobenzeneHCID 178480602HCID 178480602, compound

Product 1

HCID 15077494HCID 15077494, compoundYield 37.1%

Procedure

Starting with 1.92g (10 moles) 2,5-dichloronitrobenzene and 1.14 g (10 mmoles) of 2-mercapto-1-methylimidazole and following the procedure described in Example 1 there was obtained 1.0 g (37%) of the product as yellow prisms, mp 143°-145° C.

Sources & evidence

ORD record
ord-80760922f3e84b6e85db1f50dc591fef
Source dataset
uspto-grants-1990_11
Patent number
US04973599

Reaction notes

Loading…