Hydrochloric Acid → Phosphonic acid, [2-nitro-5-[2-nitro-4-(trifluoromethyl)phenoxy]phenyl]-

HRID 1074368Notes

Reaction equation

HRID 1074368 reaction equation
C([O:3][P:4]([C:9]1[CH:14]=[C:13]([O:15][C:16]2[CH:21]=[CH:20][C:19]([C:22]([F:25])([F:24])[F:23])=[CH:18][C:17]=2[N+:26]([O-:28])=[O:27])[CH:12]=[CH:11][C:10]=1[N+:29]([O-:31])=[O:30])(=[O:8])[O:5]CC)C.Cl>C(O)C>[N+:29]([C:10]1[CH:11]=[CH:12][C:13]([O:15][C:16]2[CH:21]=[CH:20][C:19]([C:22]([F:23])([F:24])[F:25])=[CH:18][C:17]=2[N+:26]([O-:28])=[O:27])=[CH:14][C:9]=1[P:4](=[O:3])([OH:5])[OH:8])([O-:31])=[O:30]

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 54178647HCID 54178647, compound

Product 1

HCID 20476548Phosphonic acid, [2-nitro-5-[2-nitro-4-(trifluoromethyl)phenoxy]phenyl]-

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture of 1.85 g of the 2-nitro-5-(2'-nitro-4'-trifluoromethylphenoxy)-phenylphosphonic acid diethyl ester obtained in Example 1, in 20 ml of ethanol, and 40 ml of 20% hydrochloric acid, is refluxed for 24 hours and then evaporated to dryness, affording as residue the monohydrate of the corresponding free phosphonic acid in the form of yellowish brown crystals in quantitative yield.

Workup

  1. customevaporated to dryness

Sources & evidence

ORD record
ord-53eea77846c347c18601890694e280a5
Source dataset
uspto-grants-1983_07
Patent number
US04391624

Reaction notes

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