HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diazomethane → Methyl-10,11-dihydro-11-hydroxydibenzo[b,f]thiepin-3-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diazomethane | HCID 9550 | — |
| Reactant | 10,11-Dihydro-11-hydroxydibenzo[b,f]thiepin-3-carboxylic Acid | HCID 13151856 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | Methyl-10,11-dihydro-11-hydroxydibenzo[b,f]thiepin-3-carboxylate | HCID 54217888 | — |
Reaction Steps
13.5 G. 10,11-dihydro-11-hydroxydibenzo[b,f]thiepin-3-carboxylic acid is suspended in ether and excess diazomethane is added in portions. A clear solution results which is filtered from small particles in suspension and the filtrate evaporated to dryness to a yellow oil weighing 14.2 g.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04394515 |
| Source dataset | uspto-grants-1983_07 |
| ORD ID | ord-9ba9227263fd4e38b09073962c45ec9f |
| Source note | uspto-grants-1983_07 |