Hydrogen Peroxide → HCID 178527106, compound

HRID 1074993Notes

Reaction equation

HRID 1074993 reaction equation
[NH:1]1[C:5]([C:6]2[CH:7]=[CH:8][C:9]3[CH2:15][CH2:14][C:13]4[CH:16]=[CH:17][CH:18]=[CH:19][C:12]=4[S:11][C:10]=3[CH:20]=2)=[N:4][N:3]=[N:2]1.[OH:21]O>C(O)(=O)C>[NH:1]1[C:5]([C:6]2[CH:7]=[CH:8][C:9]3[CH2:15][CH2:14][C:13]4[CH:16]=[CH:17][CH:18]=[CH:19][C:12]=4[S:11](=[O:21])[C:10]=3[CH:20]=2)=[N:4][N:3]=[N:2]1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 178419877HCID 178419877, compound

Product 1

HCID 178527106HCID 178527106, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

A mixture of 600 mg. of 10,11-dihydro-3-(5-tetrazolyl)dibenzo[b,f]thiepin, 25 cc. acetic acid and 5 cc. 30% hydrogen peroxide is stirred for 6 hours. The suspended solid is filtered, washed with acetic acid, then water and dried to yield 575 mg. of pure material, m.p. 287° C. dec.

Workup

  1. additionA mixture of 600 mg
  2. filtrationThe suspended solid is filtered
  3. washwashed with acetic acid
  4. dry with materialwater and dried
  5. customto yield 575 mg

Sources & evidence

ORD record
ord-f1b4594c3701404f9790f056da3e2ab7
Source dataset
uspto-grants-1983_07
Patent number
US04394515

Reaction notes

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