Hydrogen Peroxide → HCID 13151881, compound

HRID 1075000Notes

Reaction equation

HRID 1075000 reaction equation
[N+:1]([C:4]1[CH:5]=[CH:6][C:7]2[S:13][C:12]3[CH:14]=[C:15]([C:18]([OH:20])=[O:19])[CH:16]=[CH:17][C:11]=3[CH:10]=[CH:9][C:8]=2[CH:21]=1)([O-:3])=[O:2].[OH:22]O>C(O)(=O)C>[N+:1]([C:4]1[CH:5]=[CH:6][C:7]2[S:13](=[O:22])[C:12]3[CH:14]=[C:15]([C:18]([OH:20])=[O:19])[CH:16]=[CH:17][C:11]=3[CH:10]=[CH:9][C:8]=2[CH:21]=1)([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 13151880HCID 13151880, compound

Product 1

HCID 13151881HCID 13151881, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

400 Mg. 8-nitrodibenzo[b,f]thiepin-3-carboxylic acid is stirred for 24 hours in 200 cc. acetic acid and 1.5 cc. 30% hydrogen peroxide. The product is filtered, washed with water and dried to yield 315 mg. (74%) of pure product, m.p. 278°-281° C.

Workup

  1. filtrationThe product is filtered
  2. washwashed with water
  3. customdried
  4. customto yield 315 mg

Sources & evidence

ORD record
ord-f8dadd1cb5c44a22804fda05dd5073ae
Source dataset
uspto-grants-1983_07
Patent number
US04394515

Reaction notes

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