Hydrochloric Acid → 2,4-Diaminobenzene-1-thiol

HRID 1075333Notes

Reaction equation

HRID 1075333 reaction equation
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-])=O)[CH:7]=[CH:6][C:5]=1[SH:13])([O-])=O.Cl>[Zn]>[NH2:1][C:4]1[CH:9]=[C:8]([NH2:10])[CH:7]=[CH:6][C:5]=1[SH:13]

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 75201Benzenethiol, 2,4-dinitro-

Product 1

HCID 209786492,4-Diaminobenzene-1-thiol

Reagents, catalysts & solvents 1

HCID 23994ZincCatalyst

Procedure

Employing standard chemical reactions, the 2,4-diaminothiophenol was prepared by first reacting sodium hydrosulfide with 2,4-dinitrochlorobenzene to produce 2,4-dinitrophenylmercaptan. The 2,4-dinitrophenylmercaptan was reduced with zinc and hydrochloric acid to produce 2,4-diamino-thiophenol.

Sources & evidence

ORD record
ord-184fe4c19c2d41f4828e63efa3267b06
Source dataset
uspto-grants-1983_07
Patent number
US04395527

Reaction notes

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