HuagongsheHuagongshe Chemistry Print Report · For research reference only
Formaldehyde → HCID 131721227, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Formaldehyde | HCID 712 | — |
| Reactant | Potassium Acetate | HCID 517044 | — |
| Reactant | 2-Hydroxybutanedinitrile | HCID 21253562 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | HCID 131721227 | HCID 131721227 | — |
Reaction Steps
It is also known that malonitrile can be reacted in glacial acetic acid, in the presence of potassium acetate, with gaseous formaldehyde at 100° C. to produce bis(methylol) malonitrile (Ardis, A. E.; Averill, S. J.; Gilbert, H.; Miller, F. F.; Schmidt, R. F.; Stewart, F. D.; and Trumbull, H. L.; J. Am. Chem. Soc., 72 (1950), 1305), although the yield is only 24% of the theoretical yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05902896 |
| Source dataset | uspto-grants-1999_05 |
| ORD ID | ord-69fcaf08fbee4c609825c45931acf952 |
| Source note | uspto-grants-1999_05 |