Hydroxyamine hydrochloride → HCID 86754068, compound

HRID 1075616Notes

Reaction equation

HRID 1075616 reaction equation
[C:1]1([N:7]2[CH:11]=[CH:10][N:9]([C:12](=O)[CH3:13])[NH:8]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Cl.[NH2:16][OH:17].C([O-])(=O)C.[Na+]>C(O)C.O>[C:1]1([N:7]2[CH:11]=[CH:10][N:9]([C:12](=[N:16][OH:17])[CH3:13])[NH:8]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

5

Reactant 3

HCID 443297Hydroxyamine hydrochlorideHCID 517045Sodium AcetateHCID 54378067HCID 54378067, compound

Product 1

HCID 86754068HCID 86754068, compound

Reagents, catalysts & solvents 1

HCID 19096565Water ethanolSolvent

Conditions

Temperature
25 °C

Procedure

A mixture of 28 g (0.15 mol) of 1-phenyl-3-acetyltriazole (Example 1a), 12 g (0.19 mol) of hydroxylamine hydrochloride and 16 g (0.2 mol) of sodium acetate in 225 ml of ethanol/water 2:1 was stirred overnight at room temperature (=25° C.).

Sources & evidence

ORD record
ord-aa581a49af0f4b68ae0a8526696b9d69
Source dataset
uspto-grants-1999_05
Patent number
US05905087

Reaction notes

Loading…