Carbon Tetrachloride → 1-Chloro-cyclohexanecarbonyl chloride

HRID 1075761Notes

Reaction equation

[CH:1]1([C:7]([Cl:9])=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.C(Cl)(Cl)(Cl)[Cl:29]>>[Cl:29][C:1]1([C:7]([Cl:9])=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

Participants

Reactant 3

HCID 5943Carbon Tetrachloride

HCID 7187Benzoyl Peroxide

HCID 75938Cyclohexanecarbonyl chloride

Product 1

HCID 122282221-Chloro-cyclohexanecarbonyl chloride

Procedure

80 g (0.547 mol) of cyclohexanecarboxylic acid chloride, 30 ml of carbon tetrachloride, 63 ml (0.778 mol) of SO2Cl2 and 1.5 g of benzoyl peroxide are heated for 10 hours. The chlorinated acid chloride is then distilled from the reaction mixture.

Workup

distillationThe chlorinated acid chloride is then distilled from the reaction mixture

Sources & evidence

ORD record: ord-bc7d72b648544d949e455066e81eeec9
Source dataset: uspto-grants-1976_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03954730

Reaction notes

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