p-Fluorotoluene → HCID 19361939, compound

HRID 1076065Notes

Reaction equation

HRID 1076065 reaction equation
[CH3:1][S:2]([C:4]1[CH:12]=[CH:11][C:7]([C:8](Cl)=[O:9])=[CH:6][CH:5]=1)=[O:3].[F:13][C:14]1[CH:19]=[CH:18][C:17]([CH3:20])=[CH:16][CH:15]=1>FC(F)(F)S(O)(=O)=O>[F:13][C:14]1[CH:15]=[CH:16][C:17]([CH3:20])=[C:18]([CH:19]=1)[C:8]([C:7]1[CH:11]=[CH:12][C:4]([S:2]([CH3:1])=[O:3])=[CH:5][CH:6]=1)=[O:9]

Participants

4

Reactant 2

HCID 9603p-FluorotolueneHCID 193619424-(Methanesulfinyl)benzoyl chloride

Product 1

HCID 19361939HCID 19361939, compound

Reagents, catalysts & solvents 1

HCID 62406Trifluoromethanesulfonic acidSolvent

Procedure

p-Methylsulfinylbenzoyl chloride (0.2 mole) and p-fluorotoluene (0.2 mole) are refluxed together in trifluoromethanesulfonic acid for 6 hours according to the procedure of Chodroff and Klein, J.A.C.S. 70, 7209 (1948).

Sources & evidence

ORD record
ord-39b7bed29b164cc4aa632edc55c7c317
Source dataset
uspto-grants-1976_05
Patent number
US03954852

Reaction notes

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