Aminoacetaldehyde dimethyl acetal → HCID 178495879, compound

HRID 1076208Notes

Reaction equation

HRID 1076208 reaction equation
[CH3:1][C:2]1[CH:3]=[CH:4][C:5]2[NH:11][C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[C:8](=S)[NH:7][C:6]=2[CH:17]=1.[CH3:18][O:19][CH:20]([O:23][CH3:24])[CH2:21][NH2:22]>C(O)CCC>[CH3:18][O:19][CH:20]([O:23][CH3:24])[CH2:21][NH:22][C:8]1[C:9]2[CH:15]=[CH:14][CH:13]=[CH:12][C:10]=2[NH:11][C:5]2[CH:4]=[CH:3][C:2]([CH3:1])=[CH:17][C:6]=2[N:7]=1

Participants

4

Reactant 2

HCID 89728Aminoacetaldehyde dimethyl acetalHCID 54258643HCID 54258643, compound

Product 1

HCID 178495879HCID 178495879, compound

Reagents, catalysts & solvents 1

HCID 2631-ButanolSolvent

Procedure

In the manner given in Example 4, 8-methyl-5,10-dihydro-11H-dibenzo[b,e][1,4]diazepine-11-thione is treated with amino acetaldehyde dimethyl acetal in n-butanol to give 8-methyl-[(5H-dibenzo[b,e][1,4]diazepin-11-yl)amino]-acetaldehyde dimethyl acetal.

Sources & evidence

ORD record
ord-bdf747963de8427badd95b8b6d94789e
Source dataset
uspto-grants-1976_05
Patent number
US03956297

Reaction notes

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