m-Chloroperbenzoic acid → HCID 54195387, compound

HRID 1076344Notes

Reaction equation

HRID 1076344 reaction equation
ClC1C=CC=C(C(OO)=[O:9])C=1.[C:12]([C:14]1[CH:15]=[C:16]2[C:20](=[CH:21][CH:22]=1)[C:19](=[CH:23][C:24]1[CH:29]=[CH:28][C:27]([S:30]([CH3:32])=[O:31])=[CH:26][CH:25]=1)[C:18]([CH3:33])=[C:17]2[CH2:34][C:35]([OH:37])=[O:36])#[N:13]>CC(C)=O>[C:12]([C:14]1[CH:15]=[C:16]2[C:20](=[CH:21][CH:22]=1)[C:19](=[CH:23][C:24]1[CH:29]=[CH:28][C:27]([S:30]([CH3:32])(=[O:9])=[O:31])=[CH:26][CH:25]=1)[C:18]([CH3:33])=[C:17]2[CH2:34][C:35]([OH:37])=[O:36])#[N:13]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 54562088HCID 54562088, compound

Product 1

HCID 54195387HCID 54195387, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

5-Cyano-2-methyl-1-(p-methylsulfonylbenzylidene)-3-indenylacetic acid is prepared by the addition of 1.0 mole of m-chloroperbenzoic acid per mole of 5-cyano-2-methyl-1-(p-methylsulfinylbenzylidene)-3-indenylacetic acid in an acetone solution.

Sources & evidence

ORD record
ord-230c2a8352d94a37ad95cc768edcefb5
Source dataset
uspto-grants-1976_05
Patent number
US03956363

Reaction notes

Loading…