HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methoxymethyl isocyanate → HCID 85037874, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methoxymethyl isocyanate | HCID 62609 | — |
| Reactant | N-(5-Methyl-1,3-oxathiolan-4-ylidene)hydroxylamine | HCID 71364792 | — |
| Catalyst | Diethyl Ether | HCID 3283 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | HCID 85037874 | HCID 85037874 | — |
Reaction Steps
A quantity of 5 ml of methoxymethyl isocyanate was caused to react with 5 grams of 4-oximino-5-methyl-1,3-oxathiolane dissolved in 100 ml of anhydrous ether containing 10 drops of triethylamine over a period of 48 hours at room temperature. Conventional workup and recrystallization from isopropyl ether/ethyl acetate afforded 5.5 grams of product, mp 78°-79°; structure confirmed by spectral analysis.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03956500 |
| Source dataset | uspto-grants-1976_05 |
| ORD ID | ord-ce73f97b609f49b69b1a358cd96328e7 |
| Source note | uspto-grants-1976_05 |