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HRID1076415

反应详情

EQUATION

反应方程式

HRID 1076415 的结构方程式

REACTANTS

反应物

1
结构：CC(C)(C)OC(=O)NNC(=O)[C@H](Cc1ccccc1)NC(=O)[C@H](CC(N)=O)NC(=O)OCc1ccccc1
HCID131710203

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)OC(=O)NNC(=O)[C@H](Cc1ccccc1)NC(=O)[C@@H](N)CC(N)=O
HCID131710205

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Pd]
催化剂HCID23938

Palladium

Pd

结构：CO
溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

28.75 g of the carbobenzoxy compound of 25, dissolved in 1 liter of methanol, are hydrogenated at room temperature in the presence of 2.9 g of 10 % strength palladium-charcoal. After complete decarbobenzoxylation the catalyst is filtered off and the filtrate is evaporated to dryness. The product melts at 160°- 161°C. Rf = 0.15 in chloroform-methanol (8:2).

WORKUP

后处理

  1. filtrationAfter complete decarbobenzoxylation the catalyst is filtered off
  2. customthe filtrate is evaporated to dryness