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HRID1076764

反应详情

EQUATION

反应方程式

HRID 1076764 的结构方程式

REACTANTS

反应物

2
结构：[Na+].[OH-]
HCID14798

Sodium Hydroxide

HNaO

结构：C=C(C)C1CC=C(COC(C)=O)CC1
HCID61780

[4-(Prop-1-en-2-yl)cyclohex-1-en-1-yl]methyl acetate

C12H18O2

PRODUCTS

生成物

1
结构：C=C(C)[C@@H]1CC=C(CO)CC1
HCID369312

(4S)-4-(1-Methylethenyl)-1-cyclohexene-1-methanol

C10H16O

收率 97.7%

PROCEDURE

实验过程

Perillyl acetate (196 g.) derived from either of the examples mentioned and 30% aqueous sodium hydroxide (60 g.) were refluxed gently with stirring for 4 hours. The oil layer was separated and distilled under reduced pressure to give perillyl alcohol (150 g.) b.P. 80°/0.7 mm., αD20 + 102.5.

WORKUP

后处理

  1. customThe oil layer was separated
  2. distillationdistilled under reduced pressure