Potassium Permanganate → HCID 21538583, compound

HRID 1076914Notes

Reaction equation

HRID 1076914 reaction equation
[Mn]([O-])(=O)(=O)=O.[K+].CC1C2[O:20]C3C(=CC=CC=3C)C(=O)C=2C=CC=1.[CH:24]1[C:37]2[CH2:36][C:35]3[CH:34]=[CH:33][CH:32]=[C:31]([C:38]([OH:40])=[O:39])[C:30]=3[O:29][C:28]=2[C:27]([C:41]([OH:43])=[O:42])=[CH:26][CH:25]=1.C1(C(O)=O)C(C(O)=O)=CC=C2C=1CC1C(=CC=CC=1)O2>>[O:20]=[C:36]1[C:35]2[CH:34]=[CH:33][CH:32]=[C:31]([C:38]([OH:40])=[O:39])[C:30]=2[O:29][C:28]2[C:27]([C:41]([OH:43])=[O:42])=[CH:26][CH:25]=[CH:24][C:37]1=2

Participants

5

Reactant 4

HCID 516875Potassium PermanganateHCID 14612562HCID 14612562, compoundHCID 21538578HCID 21538578, compoundHCID 23374742HCID 23374742, compound

Product 1

HCID 21538583HCID 21538583, compound

Procedure

9-Oxoxanthene-4,5-dicarboxylic acid which is prepared by potassium permanganate oxidation of the corresponding 4,5-dimethylxanthen-9-one [M. Schopff, Ber. 25, 3647 (1892)]49 is reduced to xanthene-4,5-dicarboxylic acid by a Wolff-Kishner reduction (N. Ishikawa, Yuki Gose: Kagaku Kyokai Shi 17, 553-6 (1959); CA 54:450]. The xanthene dicarboxylic acid derivative is converted to xanthene-4,5-dipiperidide by conventional procedures.

Sources & evidence

ORD record
ord-e7f6169abeec4e498eb05279c0d872c7
Source dataset
uspto-grants-1976_05
Patent number
US03957989

Reaction notes

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