1,1,1,3,3,3-Hexachloro-2,2-difluoropropane → 1,1,3,3-Tetrachloro-2,2-difluoropropane

HRID 1078075Notes

Reaction equation

HRID 1078075 reaction equation
[C:1]([C:5]([C:8](Cl)([Cl:10])[Cl:9])([F:7])[F:6])(Cl)([Cl:3])[Cl:2].C(C(C(Cl)(Cl)Cl)(F)F)(Cl)Cl>>[CH:1]([C:5]([CH:8]([Cl:10])[Cl:9])([F:7])[F:6])([Cl:3])[Cl:2]

Participants

3

Reactant 2

HCID 766501,1,1,3,3,3-Hexachloro-2,2-difluoropropaneHCID 1502501,1,3,3,3-Pentachloro-2,2-difluoropropane

Product 1

HCID 150848811,1,3,3-Tetrachloro-2,2-difluoropropane

Procedure

The reaction was conducted and the product was analyzed in the same manner as in Example 1-1 except that 34 g (0.12 mol) of CCl3CF2CCl3 was used. As a result, it was found that the conversion was 84%, and CHCl2CF2CCl3 formed at a selectivity of 46% and CHCl2CF2CHCl2 formed at a selectivity of 44%.

Sources & evidence

ORD record
ord-8b3209dbf6a44e4b8fd1bb65bfb5f113
Source dataset
uspto-grants-1996_08
Patent number
US05545777

Reaction notes

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