Sodium → HCID 54524162, compound

Participants

Reaction Steps

Ethyl 2-deoxy-2-phthalamido-3,4,6-tri-O-acetyl-β-D-glucopyranosyide (compound 13) from example 17 was taken up in 100 mL of dry methanol and treated with 100 mg of sodium metal. The solution was stirred at room temperature for 24 hours and then neutralized with Amberlite [R-120(H+)] resin, filtered, and evaporated to dryness in vacuo. This compound was used in the preparation of compound 15 and compound 66.

Provenance & Evidence