2-(m-Chlorophenoxy)propionic acid → HCID 15839964, compound

HRID 1079453Notes

Reaction equation

HRID 1079453 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH:11]=[CH:12][CH:13]=1)[O:5][CH:6]([CH3:10])[C:7]([OH:9])=O.[N+]([O-])(O)=O.[O:18]([CH2:22][CH2:23][NH2:24])[N+:19]([O-:21])=[O:20].C(OC(C)C)(C)C>>[O:18]([CH2:22][CH2:23][NH:24][C:7](=[O:9])[CH:6]([O:5][C:4]1[CH:11]=[CH:12][CH:13]=[C:2]([Cl:1])[CH:3]=1)[CH3:10])[N+:19]([O-:21])=[O:20]

Participants

4

Reactant 3

HCID 75422-(m-Chlorophenoxy)propionic acidHCID 7914Diisopropyl EtherHCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)

Product 1

HCID 15839964HCID 15839964, compoundYield 56.8%

Procedure

Following a similar treatment to that in Example 2 and using 0.71 g of 2-(3-chlorophenoxy)propionic acid and 0.6 g of 2-nitroxyethylamine nitrate, 0.58 g of the title compound was obtained as colorless acicular prisms (solvent for recrystallization; diisopropyl ether).

Sources & evidence

ORD record
ord-9dce99adaafe496c9d90aa6aea247779
Source dataset
uspto-grants-1996_12
Patent number
US05580893

Reaction notes

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