Diisopropyl Ether → HCID 15839968, compound

HRID 1079456Notes

Reaction equation

[O:1]([CH:8]([CH2:12][CH3:13])[C:9]([OH:11])=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N+]([O-])(O)=O.[O:18]([CH2:22][CH2:23][NH2:24])[N+:19]([O-:21])=[O:20].C(OC(C)C)(C)C>>[O:18]([CH2:22][CH2:23][NH:24][C:9](=[O:11])[CH:8]([O:1][C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1)[CH2:12][CH3:13])[N+:19]([O-:21])=[O:20]

Participants

Reactant 3

HCID 7914Diisopropyl Ether

HCID 579872-Phenoxybutanoic acid

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)

Product 1

HCID 15839968HCID 15839968, compoundYield 57.8%

Procedure

Following a similar treatment to that in Example 2 and using 0.64 g of 2-phenoxybutyric acid and 0.60 g of 2-nitroxyethylamine nitrate, 0.55 g of the title compound was obtained as colorless acicular prisms (solvent for recrystallization; diisopropyl ether).

Sources & evidence

ORD record: ord-e96571ea6213479b8cde6640c4779d1e
Source dataset: uspto-grants-1996_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05580893

Reaction notes

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