Diisopropyl Ether → HCID 15839969, compound

HRID 1079457Notes

Reaction equation

HRID 1079457 reaction equation
[O:1]([CH:8]([CH3:12])[C:9]([OH:11])=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N+]([O-])(O)=O.[O:17]([CH2:21][CH2:22][NH2:23])[N+:18]([O-:20])=[O:19].C(OC(C)C)(C)C>>[O:17]([CH2:21][CH2:22][NH:23][C:9](=[O:11])[CH:8]([O:1][C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1)[CH3:12])[N+:18]([O-:20])=[O:19]

Participants

4

Reactant 3

HCID 7914Diisopropyl EtherHCID 13658DL-2-Phenoxypropionic acidHCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)

Product 1

HCID 15839969HCID 15839969, compoundYield 54.3%

Procedure

Following a similar treatment to that in Example 2 and using 0.71 g of 2-phenoxypropionic acid and 0.60 g of 2-nitroxyethylamine nitrate, 0.49 g of the title compound was obtained as colorless needles (solvent for recrystallization; diisopropyl ether).

Sources & evidence

ORD record
ord-15970802b5a34d65b540199bfdbb2ae2
Source dataset
uspto-grants-1996_12
Patent number
US05580893

Reaction notes

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