Diisopropyl Ether → HCID 15839974, compound

HRID 1079462Notes

Reaction equation

[CH3:1][C:2]1[O:6][N:5]=[C:4]([O:7][CH2:8][C:9]([OH:11])=O)[CH:3]=1.[N+]([O-])(O)=O.[O:16]([CH2:20][CH2:21][NH2:22])[N+:17]([O-:19])=[O:18].C(OC(C)C)(C)C>>[O:16]([CH2:20][CH2:21][NH:22][C:9](=[O:11])[CH2:8][O:7][C:4]1[CH:3]=[C:2]([CH3:1])[O:6][N:5]=1)[N+:17]([O-:19])=[O:18]

Participants

Reactant 3

HCID 7914Diisopropyl Ether

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)

HCID 4962137Acetic acid, [(5-methyl-3-isoxazolyl)oxy]- (9CI)

Product 1

HCID 15839974HCID 15839974, compoundYield 36.9%

Procedure

Following a similar treatment to that in Example 2 and using 0.40 g of 5-methyl-3-isoxazolyloxyacetic acid and 0.43 g of nitroxyethylamine nitrate, 0.23 g of the title compound was obtained as colorless needles (solvent for recrystallization; diisopropyl ether).

Sources & evidence

ORD record: ord-1dcef0ab2bc547b1944a332cf5a0dafe
Source dataset: uspto-grants-1996_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05580893

Reaction notes

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