Diisopropyl Ether → HCID 23367102, compound

HRID 1079463Notes

Reaction equation

HRID 1079463 reaction equation
[C:1]1([C:7]2[O:11][N:10]=[C:9]([O:12][CH2:13][C:14]([OH:16])=O)[CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[N+]([O-])(O)=O.[O:21]([CH2:25][CH2:26][NH2:27])[N+:22]([O-:24])=[O:23].C(OC(C)C)(C)C>>[O:21]([CH2:25][CH2:26][NH:27][C:14](=[O:16])[CH2:13][O:12][C:9]1[CH:8]=[C:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[O:11][N:10]=1)[N+:22]([O-:24])=[O:23]

Participants

4

Reactant 3

HCID 7914Diisopropyl EtherHCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)HCID 23367105HCID 23367105, compound

Product 1

HCID 23367102HCID 23367102, compoundYield 53.2%

Procedure

Following a similar treatment to that in Example 2 and using 0.78 g of 5-phenyl-3-isoxazolyloxyacetic acid and 0.60 g of nitroxyethylamine nitrate, 0.58 g of the title compound was obtained as colorless needles (solvent for recrystallization; diisopropyl ether).

Sources & evidence

ORD record
ord-7bc0cb5187fb4db586ff349c043fece0
Source dataset
uspto-grants-1996_12
Patent number
US05580893

Reaction notes

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