Diisopropyl Ether → HCID 23367110, compound

HRID 1079464Notes

Reaction equation

[C:1]1([C:7]2[O:11][N:10]=[C:9]([O:12][CH2:13][C:14]([OH:16])=O)[C:8]=2[Cl:17])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[N+]([O-])(O)=O.[O:22]([CH2:26][CH2:27][NH2:28])[N+:23]([O-:25])=[O:24].C(OC(C)C)(C)C>>[O:22]([CH2:26][CH2:27][NH:28][C:14](=[O:16])[CH2:13][O:12][C:9]1[C:8]([Cl:17])=[C:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[O:11][N:10]=1)[N+:23]([O-:25])=[O:24]

Participants

Reactant 3

HCID 7914Diisopropyl Ether

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)

HCID 13050996HCID 13050996, compound

Product 1

HCID 23367110HCID 23367110, compoundYield 45.2%

Procedure

Following a similar treatment to that in Example 2 and using 0.70 g of 5-phenyl-4-chloro-3-isoxazolyloxyacetic acid and 0.46 g of nitroxyethylamine nitrate, 0.42 g of the title compound was obtained as colorless needles (solvent for recrystallization; diisopropyl ether).

Sources & evidence

ORD record: ord-5e8e657832984f2ba100d7f2152ae73f
Source dataset: uspto-grants-1996_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05580893

Reaction notes

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