Diisopropyl Ether → HCID 23367121, compound

HRID 1079469Notes

Reaction equation

HRID 1079469 reaction equation
[Br:1][C:2]1[O:6][C:5]([C:7]([OH:9])=O)=[CH:4][CH:3]=1.[N+]([O-])(O)=O.[O:14]([CH2:18][CH2:19][NH2:20])[N+:15]([O-:17])=[O:16].C(OC(C)C)(C)C>>[O:14]([CH2:18][CH2:19][NH:20][C:7]([C:5]1[O:6][C:2]([Br:1])=[CH:3][CH:4]=1)=[O:9])[N+:15]([O-:17])=[O:16]

Participants

4

Reactant 3

HCID 7914Diisopropyl EtherHCID 685115-Bromo-2-furanecarboxylic acidHCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)

Product 1

HCID 23367121HCID 23367121, compoundYield 22.2%

Procedure

Following a similar treatment to that in Example 2 and using 0.68 g of 5-bromo-2-furancarboxylic acid and 0.60 g of nitroxyethylamine nitrate, 0.22 g of the title compound was obtained as pale yellow acicular prisms (solvent for recrystallization; diisopropyl ether).

Sources & evidence

ORD record
ord-db9da67d290d43eeac9af4bc2d71567f
Source dataset
uspto-grants-1996_12
Patent number
US05580893

Reaction notes

Loading…