Diisopropyl Ether → HCID 23367112, compound

HRID 1079471Notes

Reaction equation

HRID 1079471 reaction equation
[CH3:1][C:2]1[CH:6]=[CH:5][S:4][C:3]=1[C:7]([OH:9])=O.[N+]([O-])(O)=O.[O:14]([CH2:18][CH2:19][NH2:20])[N+:15]([O-:17])=[O:16].C(OC(C)C)(C)C>>[O:14]([CH2:18][CH2:19][NH:20][C:7]([C:3]1[S:4][CH:5]=[CH:6][C:2]=1[CH3:1])=[O:9])[N+:15]([O-:17])=[O:16]

Participants

4

Reactant 3

HCID 7914Diisopropyl EtherHCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)HCID 902693-Methyl-2-thenoic acid

Product 1

HCID 23367112HCID 23367112, compoundYield 42.8%

Procedure

Following a similar treatment to that in Example 2 and using 0.60 g of 3-methyl-2-thiophenecarboxylic acid and 0.60 g of nitroxyethylamine nitrate, 0.35 g of the title compound was obtained as colorless needles (solvent for recrystallization; diisopropyl ether).

Sources & evidence

ORD record
ord-2fca10bd2cfd42bdb3c571d6594b8f73
Source dataset
uspto-grants-1996_12
Patent number
US05580893

Reaction notes

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