Sodium Azide → HCID 178437485, compound

HRID 1081914Notes

Reaction equation

HRID 1081914 reaction equation
[CH2:1]([C:3]1[N:7]([CH2:8][C:9]2[CH:14]=[CH:13][C:12]([C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=3[C:21]#[N:22])=[CH:11][CH:10]=2)[C:6]2[CH:23]=[C:24]([N:27]([CH3:37])[S:28]([C:31]3[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=3)(=[O:30])=[O:29])[CH:25]=[CH:26][C:5]=2[N:4]=1)[CH3:2].[N-:38]=[N+:39]=[N-:40].[Na+]>CN(C)C=O>[CH2:1]([C:3]1[N:7]([CH2:8][C:9]2[CH:10]=[CH:11][C:12]([C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=3[C:21]3[NH:40][N:39]=[N:38][N:22]=3)=[CH:13][CH:14]=2)[C:6]2[CH:23]=[C:24]([N:27]([CH3:37])[S:28]([C:31]3[CH:32]=[CH:33][CH:34]=[CH:35][CH:36]=3)(=[O:29])=[O:30])[CH:25]=[CH:26][C:5]=2[N:4]=1)[CH3:2]

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 57064115HCID 57064115, compound

Product 1

HCID 178437485HCID 178437485, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Prepared analogously to Example 41 from 4'-[[2-ethyl-6-(N-benzenesulphonyl-methylamino)-benzimidazol-1-yl]methyl]-2-cyano-biphenyl and sodium azide in dimethylformamide.

Sources & evidence

ORD record
ord-43117846ca33478298e514cf5dd4e941
Source dataset
uspto-grants-1996_12
Patent number
US05587393

Reaction notes

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