HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 14118983, compound → HCID 19969441, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 14118983 | HCID 14118983 | — |
| Catalyst | Adams' catalyst | HCID 345198 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | HCID 19969441 | HCID 19969441 | 65.8% |
Reaction Steps
2-Nitro-10,11-dihydrodibenzo[b,f][1,4]thiazepin-11-one (0.82 g) was dissolved in warm acetic acid (100 ml) and the resulting solution hydrogenated over Adam's catalyst (80 mg) for 3 hours at atmospheric pressure. The catalyst was filtered off and the solution evaporated to dryness. Recrystallisation of the residue from methanol gave the product as a greenish powder (0.48 g, m/s. M- =242).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05589474 |
| Source dataset | uspto-grants-1996_12 |
| ORD ID | ord-150dd6df93194a7bab85898e74fe5d5c |
| Source note | uspto-grants-1996_12 |