HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl Peroxide → 2-(Bromomethyl)-5-phenylpyridine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl Peroxide | HCID 7187 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 2-Methyl-5-phenylpyridine | HCID 76744 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 2-(Bromomethyl)-5-phenylpyridine | HCID 15171301 | — |
Reaction Steps
To a solution of 2-methyl-5-phenylpyridine (step 1) (169 mg) and N-bromosuccinimide (177 mg) in CCl4 (3 cc) was added benzoyl peroxide (25 mg) and the mixture irradiated with visible light for 5 hours under reflux. After removal of the solvent the residue was purified by chromatography to afford the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05004743 |
| Source dataset | uspto-grants-1991_04 |
| ORD ID | ord-a97a4472755f4342acbde25e2376e4dd |
| Source note | uspto-grants-1991_04 |