N-bromobutanimide → 4-(Bromomethyl)-5-methyl-1,3-dioxol-2-one
Reaction equation
[CH3:1][C:2]1[O:3][C:4](=[O:8])[O:5][C:6]=1[CH3:7].[Br:9]N1C(=O)CCC1=O>C(Cl)(Cl)(Cl)Cl>[Br:9][CH2:1][C:2]1[O:3][C:4](=[O:8])[O:5][C:6]=1[CH3:7]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
According to the method described in Liebigs. Ann. Chem., 1977, 27-32 4,5-dimethyl-1,3-dioxole-2-one (500 mg, 4.38 mmol) and N-bromosuccinimide (0.78 g, 4.38 mmol) were heated under reflux in dry carbon tetrachloride in the presence of α-α'-azobisisobutyronitrile (7.5 mg) for 20 minutes.
Sources & evidence
- ORD record
- ord-1a67a1809430482ab1aa7b37fe17b1b9
- Source dataset
- uspto-grants-1991_04
- Patent number
- US05006548
Reaction notes
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