HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-bromobutanimide → 4-(Bromomethyl)-5-methyl-1,3-dioxol-2-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 4,5-Dimethyl-1,3-dioxol-2-one | HCID 142210 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 4-(Bromomethyl)-5-methyl-1,3-dioxol-2-one | HCID 10774141 | — |
Reaction Steps
According to the method described in Liebigs. Ann. Chem., 1977, 27-32 4,5-dimethyl-1,3-dioxole-2-one (500 mg, 4.38 mmol) and N-bromosuccinimide (0.78 g, 4.38 mmol) were heated under reflux in dry carbon tetrachloride in the presence of α-α'-azobisisobutyronitrile (7.5 mg) for 20 minutes.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05006548 |
| Source dataset | uspto-grants-1991_04 |
| ORD ID | ord-1a67a1809430482ab1aa7b37fe17b1b9 |
| Source note | uspto-grants-1991_04 |