Hydrochloric Acid → HCID 13920682, compound

HRID 1084963Notes

Reaction equation

HRID 1084963 reaction equation
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][O:8][CH2:9]/[CH:10]=[CH:11]\[C:12]1[CH:17]=[CH:16][C:15]([NH:18][S:19]([CH3:22])(=[O:21])=[O:20])=[CH:14][CH:13]=1.[CH2:23]([NH2:30])[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1.[ClH:31]>O>[ClH:31].[C:24]1([CH2:23][NH:30][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][O:8][CH2:9]/[CH:10]=[CH:11]\[C:12]2[CH:17]=[CH:16][C:15]([NH:18][S:19]([CH3:22])(=[O:21])=[O:20])=[CH:14][CH:13]=2)[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 7504BenzylamineHCID 13920680HCID 13920680, compound

Product 1

HCID 13920682HCID 13920682, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

(Z)-N-[4-[3-[(6-Bromohexyl)oxy]-1-propenyl]phenyl]methanesulphonamide (2.0 g) was added to benzylamine (6 ml) at 125°, under nitrogen. The reaction mixture was stirred at 125° for 3 h, cooled to room temperature and added to 2N hydrochloric acid (50 ml) and water (20 ml). The resultant white solid was collected by filtration, washed in turn with 2N hydrochloric acid, water and ether then dried in vacuo at 50° to give the title compound as a white powder (1.0 g) m.p. 133°-134°.

Workup

  1. filtrationThe resultant white solid was collected by filtration
  2. washwashed in turn with 2N hydrochloric acid, water and ether
  3. customthen dried in vacuo at 50°

Sources & evidence

ORD record
ord-2e9300f296ba4219a600cc58f92499ea
Source dataset
uspto-grants-1991_04
Patent number
US05006556

Reaction notes

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