HCID 20059503, compound → HCID 20059512, compound

HRID 1086057Notes

Reaction equation

HRID 1086057 reaction equation
[NH2:1][C:2]1[C:18]([Cl:19])=[CH:17][C:5]([C:6]([NH:8][CH:9]2[CH:14]3[CH2:15][CH2:16][N:11]([CH2:12][CH2:13]3)[CH2:10]2)=[O:7])=[C:4]([O:20][CH2:21][CH2:22][S:23][CH3:24])[CH:3]=1.I([O-])(=O)(=O)=[O:26].[Na+]>Cl>[NH2:1][C:2]1[C:18]([Cl:19])=[CH:17][C:5]([C:6]([NH:8][CH:9]2[CH:14]3[CH2:15][CH2:16][N:11]([CH2:12][CH2:13]3)[CH2:10]2)=[O:7])=[C:4]([O:20][CH2:21][CH2:22][S:23]([CH3:24])=[O:26])[CH:3]=1

Participants

4

Reactant 2

HCID 20059503HCID 20059503, compoundHCID 23667635Sodium periodate

Product 1

HCID 20059512HCID 20059512, compound

Reagents, catalysts & solvents 1

HCID 313Hydrochloric AcidSolvent

Procedure

The product from Example 81 was oxidized in 1.4N HCl solution with sodium metaperiodate at 0°-5° C. for 2 h to give the title compound.

Sources & evidence

ORD record
ord-88180a8d096d430ea0d90cd3035c129b
Source dataset
uspto-grants-1991_04
Patent number
US05011992

Reaction notes

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