HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Ethyl-3,3-bis(4-fluorophenyl)-2-propenol → 2-Ethyl-3,3-bis(4-fluorophenyl)-2-propenal
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Ethyl-3,3-bis(4-fluorophenyl)-2-propenol | HCID 15133049 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 2-Ethyl-3,3-bis(4-fluorophenyl)-2-propenal | HCID 15133055 | 99.4% |
Reaction Steps
Activated manganese dioxide (49 g) was added to a solution of 2-ethyl-3,3-bis(4-fluorophenyl)-2-propenol (7 g, 25.5 mmol) in 100 mL of methylene chloride and the mixture stirred for 18 hours. The insolubles were removed and the solution concentrated in vacuo to give 6.9 g of the title compound as an oil. MS(CI): m/e =272 for M+ of C17H14F2O.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05011947 |
| Source dataset | uspto-grants-1991_04 |
| ORD ID | ord-81efca05a4e642eab12275043086807e |
| Source note | uspto-grants-1991_04 |