Hydrogen Peroxide → Dodecanediperoxoic acid

HRID 1086398Notes

Reaction equation

HRID 1086398 reaction equation
S(=O)(=O)(O)[OH:2].[OH:6][OH:7].[C:8]([OH:23])(=[O:22])[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][C:19](O)=[O:20]>>[C:8]([O:23][OH:2])(=[O:22])[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][C:19]([O:6][OH:7])=[O:20]

Participants

4

Reactant 3

HCID 784Hydrogen PeroxideHCID 1118Sulfuric AcidHCID 12736Dodecanedioic Acid

Product 1

HCID 105355Dodecanediperoxoic acid

Procedure

A mixture comprising 5750 g of 96% sulfuric acid and 2350 g of 40% hydrogen peroxide was introduced into a stirred vessel and treated with 1060 g of powdered dodecanedioic acid (DDA) at 45° C. over 30 minutes. After 4 hours of reaction time, a mixture of the following composition was obtained:

Workup

  1. additionwas introduced into a stirred vessel
  2. customAfter 4 hours of reaction time
  3. additiona mixture of the following composition
  4. customwas obtained

Sources & evidence

ORD record
ord-feadd71a74e14f67b6cdb7d6c3956633
Source dataset
uspto-grants-1991_07
Patent number
US05030381

Reaction notes

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