Dodecanenitrile → HCID 14651795, compound

HRID 1086437Notes

Reaction equation

HRID 1086437 reaction equation
[CH2:1]([C:12]#N)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH:14]([NH:17][CH2:18][CH2:19][NH2:20])([CH3:16])[CH3:15]>C(=S)=S>[CH:14]([N:17]1[CH2:18][CH2:19][N:20]=[C:11]1[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:1][CH3:12])([CH3:16])[CH3:15]

Participants

4

Reactant 2

HCID 17092DodecanenitrileHCID 88098N-Isopropylethylenediamine

Product 1

HCID 14651795HCID 14651795, compoundYield 82.3%

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

18.324 g of Undecyl cyanide, 15.12 g of N-isopropylethylenediamine and 0.5 ml of carbon disulfide were heated at 125° C. for 24 hrs. and worked up as mentioned under Example 23, followed by distillation at 150° C./1.2 mm gave 21.93 g (82.3%) of the product.

Workup

  1. distillationfollowed by distillation at 150° C./1.2 mm

Sources & evidence

ORD record
ord-5be30f23cd2449618966b040ed7cfe5f
Source dataset
uspto-grants-1991_07
Patent number
US05030629

Reaction notes

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