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HRID1086909

反应详情

EQUATION

反应方程式

HRID 1086909 的结构方程式

REACTANTS

反应物

2
结构：CCC[CH2][Sn](=[O])[CH2]CCC
HCID61221

Dibutylstannane oxide

C8H18OSn

结构：CC(C)CCCCCC(S)C(=O)[O-]
HCID21895674

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)CCCCCC(S)C(=O)[O-].CC(C)CCCCCC(S)C(=O)[O-].CCC[CH2][Sn+2][CH2]CCC
HCID21981422

未命名化合物

收率 102.6%

CONDITIONS

反应条件

温度
110 °C

PROCEDURE

实验过程

A suitable reactor was charged with 248.7 grams (1.0 mole) of dibutyltin oxide and 425.4 grams (2.05 moles) of isooctylthioglycolate of commercial purity. The reaction mixture was heated under vacuum, with agitation, to about 110° C. while distilling off water of reaction. On cooling and filtering, 656.1 grams of dibutyltin bis(isooctylthioglycolate) was obtained as an oily liquid.

WORKUP

后处理

  1. distillationwhile distilling off
  2. customwater of reaction
  3. temperatureOn cooling
  4. filtrationfiltering