Carbon Tetrachloride → HCID 14046523, compound

HRID 1087934Notes

Reaction equation

HRID 1087934 reaction equation
[C:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][N:5]=1)([CH3:3])=[CH2:2].[Cl:10]N1C(=O)CCC1=O.C(Cl)(Cl)(Cl)Cl>CCCCCC>[Cl:10][CH2:2][C:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][N:5]=1)=[CH2:3]

Participants

5

Reactant 3

HCID 5943Carbon TetrachlorideHCID 31398ChlorosuccinimideHCID 810072-(Prop-1-en-2-yl)pyridine

Product 1

HCID 14046523HCID 14046523, compoundYield 19.4%

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

A mixture of 4.0 g of 2-isopropenylpyridine, 4.5 g of N-chlorosuccinimide and 8 ml of carbon tetrachloride was stirred at 150° to 160° C. for 20 minutes. After the reaction mixture was cooled to room temperature, n-hexane was added thereto to remove the insoluble matter through filtration. After distilling off the solvent, the residue was purified by silica gel column chromatography (eluted with n-hexane-ethyl acetate 20:1) to obtain 1.0 g of the objective compound.

Workup

  1. customto remove the insoluble matter
  2. filtrationthrough filtration
  3. distillationAfter distilling off the solvent
  4. customthe residue was purified by silica gel column chromatography (eluted with n-hexane-ethyl acetate 20:1)

Sources & evidence

ORD record
ord-5cd26bfdec634c658f993b32f19a5671
Source dataset
uspto-grants-1990_10
Patent number
US04960897

Reaction notes

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