Carbon Tetrachloride → HCID 15008717, compound

HRID 1087941Notes

Reaction equation

HRID 1087941 reaction equation
[C:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([CH3:10])[N:5]=1)([CH3:3])=[CH2:2].[Cl:11]N1C(=O)CCC1=O.C(Cl)(Cl)(Cl)Cl>CCCCCC>[Cl:11][CH2:2][C:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([CH3:10])[N:5]=1)=[CH2:3]

Participants

5

Reactant 3

HCID 5943Carbon TetrachlorideHCID 31398ChlorosuccinimideHCID 22164279HCID 22164279, compound

Product 1

HCID 15008717HCID 15008717, compoundYield 33.9%

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

A mixture of 4.7 g of 2-isopropenyl-6-methylpyridine, 4.7 g of N-chlorosuccinimide and 10 ml of carbon tetrachloride was stirred at 150° to 160° C. for 30 minutes. After the reaction mixture was cooled to room temperature, n-hexane was added thereto to remove the insoluble matter through filtration. After distilling off the solvent, the residue was purified by silica gel column chromatography (eluted with n-hexane-ethyl acetate 20:1). to obtain 2.0 g of the objective compound.

Workup

  1. customto remove the insoluble matter
  2. filtrationthrough filtration
  3. distillationAfter distilling off the solvent
  4. customthe residue was purified by silica gel column chromatography (eluted with n-hexane-ethyl acetate 20:1)

Sources & evidence

ORD record
ord-d3dcc54b7baa4051a1b493957cbb7ee1
Source dataset
uspto-grants-1990_10
Patent number
US04960897

Reaction notes

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