참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | Toluene | HCID 1140 | — |
| 반응물 | 1,2,3,4-Tetrahydro-1-naphthalenol | HCID 10723 | — |
| 반응물 | 1-Tetralone | HCID 10724 | — |
| 촉매 | Copper dihydroxide | HCID 164826 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Tetralin | HCID 8404 | — |
반응 단계
Tetralone (132 g), toluene (131 g), and 0.5 g of copper hydroxide suspension (37.5% Cu(OH)2), were mixed into a 500 ml round bottom with temperature control, gas dispersion tube, water-cooled condenser and a magnetic stirrer. The reaction was maintained at 80° C. for 9.8 hr. with a 300 ml/minute oxygen flow at atmospheric pressure. GC analysis (area %) indicates 3% 1-tetralol, 5.2% 1-tetralone and 15% 1-tetralin hydroperoxide.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04960944 |
|---|
| 출처 데이터셋 | uspto-grants-1990_10 |
|---|
| ORD ID | ord-5d11b18391fb4479a811ec1fe8b4031f |
|---|
| 출처 메모 | uspto-grants-1990_10 |
|---|
