Hydrochloric Acid → HCID 13785667, compound

HRID 1088021Notes

Reaction equation

HRID 1088021 reaction equation
[Cl:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][C:5](C2C=CC=CC=2S([O-])(=O)=O)=[C:4]([CH3:21])[CH:3]=1.[OH-:22].[Na+].Cl>O>[Cl:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][C:5]([OH:22])=[C:4]([CH3:21])[CH:3]=1

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 14798Sodium HydroxideHCID 22164500HCID 22164500, compound

Product 1

HCID 13785667HCID 13785667, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

84.2 (0.26 mol) of the ester from step 2 are suspended in 1 l of water and mixed with 30.8 g (0.77 mol) of sodium hydroxide platelets. After 2 hours cooking under reflux the starting material is cooled and the solution is adjusted to a pH value of 2.1 with 2 N hydrochloric acid. The precipitated material is filtered by suction, washed with water and dried in vacuum at 50° C. The yield amounts to about 45.6 g 95.4% of the theoretical yield).

Workup

  1. temperatureunder reflux the starting material
  2. temperatureis cooled
  3. filtrationThe precipitated material is filtered by suction
  4. washwashed with water
  5. customdried in vacuum at 50° C
  6. customtheoretical yield)

Sources & evidence

ORD record
ord-1bc42961b19f41b284e79ae10e8a600c
Source dataset
uspto-grants-1990_10
Patent number
US04960955

Reaction notes

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